Issue 37, 2011
From the journal:

Chemical Communications

Ti/Pd-promoted intramolecular Michael-type addition of allylic carboxylates to activated alkenes†

Alba Millán,a   Ana Martín-Lasanta,a   Delia Miguel,*a   Luis Álvarez de Cienfuegos*a  and  Juan M. Cuerva*a  

* Corresponding authors

a Departamento de Química Orgánica, Universidad de Granada, Granada, Spain
E-mail: jmcuerva@ugr.es, lac@ugr.es, dmalvarez@ugr.es

Abstract

An interesting protocol for the synthesis of different vinyl substituted carbo- and heterocycles based on a new intramolecular Michael-type reaction using allylic carboxylates as pronucleophiles is reported. The success of the catalytic process is based on the excellent cooperation between the late transition metal (palladium) and the radical reagent (titanium).

Graphical abstract: Ti/Pd-promoted intramolecular Michael-type addition of allylic carboxylates to activated alkenes

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Article information

DOI
https://doi.org/10.1039/C1CC14573H
Article type
Communication
Submitted
26 Jul 2011
Accepted
09 Aug 2011
First published
22 Aug 2011

Chem. Commun., 2011,47, 10470-10472

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Ti/Pd-promoted intramolecular Michael-type addition of allylic carboxylates to activated alkenes

A. Millán, A. Martín-Lasanta, D. Miguel, L. Á. D. Cienfuegos and J. M. Cuerva, Chem. Commun., 2011, 47, 10470 DOI: 10.1039/C1CC14573H

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