Study of the incorporation and release of the non-conventional half-sandwich ruthenium(II) metallodrug RAPTA-C on a robust MOF

Elsa Quartapelle Procopio; Sara Rojas; Natalia M. Padial; Simona Galli; Norberto Masciocchi; Fátima Linares; Delia Miguel; J. Enrique Oltra; Jorge A. R. Navarro; Elisa Barea

doi:10.1039/C1CC14594K

Study of the incorporation and release of the non-conventional half-sandwich ruthenium(ii) metallodrug RAPTA-C on a robust MOF†

Elsa Quartapelle Procopio,^a Sara Rojas,^a Natalia M. Padial,^b Simona Galli,^c Norberto Masciocchi,^c Fátima Linares,^a Delia Miguel,^b J. Enrique Oltra,^b Jorge A. R. Navarro*^a and Elisa Barea*^a

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^a Universidad de Granada, Departamento de Química Inorganica, 18071 Granada, Spain
E-mail: ebaream@ugr.es; jarn@ugr.es
Fax: +34 958 248526
Tel: +34 958 248093

^b Universidad de Granada, Departamento de Química Organica, 18071 Granada, Spain

^c Dipartimento di Scienze Chimiche e Ambientali, Università dell'Insubria, 22100 Como, Italy

Abstract

The highly porous and robust [Ni₈(OH)₄(OH₂)₂(4,4′-(buta-1,3-diyne-1,4-diyl)bispyrazolato)₆]_n MOF can be used as a proof of concept for the incorporation and release of the non-conventional [Ru(p-cymene)Cl₂(pta)] RAPTA-C metallodrug.

Chemical Communications

Study of the incorporation and release of the non-conventional half-sandwich ruthenium(ii) metallodrug RAPTA-C on a robust MOF†

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Study of the incorporation and release of the non-conventional half-sandwich ruthenium(II) metallodrug RAPTA-C on a robust MOF

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