Abstract
Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre.
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Supplementary files
Article information
- Article type
- Communication
- Submitted
- 03 Aug 2011
- Accepted
- 23 Sep 2011
- First published
- 10 Oct 2011
Chem. Commun., 2011,47, 12765-12767
Permissions
pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes
C. M. Álvarez, R. Carrillo, R. García-Rodríguez and D. Miguel, Chem. Commun., 2011, 47, 12765 DOI: 10.1039/C1CC14799D
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