Issue 43, 2011
From the journal:

Chemical Communications

A chiral tetragonal magnesium-carboxylate framework with nanotubular channels†

Qipu Lin,a   Tao Wu,a   Shou-Tian Zheng,b   Xianhui Bu*b  and  Pingyun Feng*a  

* Corresponding authors

a Department of Chemistry, University of California, Riverside, USA
E-mail: pingyun.feng@ucr.edu
Fax: +1 951-827-4713
Tel: +1 951-827-2042

b Department of Chemistry and Biochemistry, California State University, Long Beach, USA
E-mail: xbu@csulb.edu
Fax: +1 562-985-8557
Tel: +1 562-985-4843

Abstract

Reported here is a rare example of a highly symmetrical chiral Mg-based MOF (CPF-1) with nanotubular channels, built from 41 (or 43) helical chains. It exhibits a high gas sorption capacity (ca. 1.29 wt% H2 at 77 K, 1 atm; 84 cm3 g−1 of CO2 at 273 K, 1 atm).

Graphical abstract: A chiral tetragonal magnesium-carboxylate framework with nanotubular channels

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Article information

DOI
https://doi.org/10.1039/C1CC14836B
Article type
Communication
Submitted
05 Aug 2011
Accepted
29 Sep 2011
First published
07 Oct 2011

Chem. Commun., 2011,47, 11852-11854

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A chiral tetragonal magnesium-carboxylate framework with nanotubular channels

Q. Lin, T. Wu, S. Zheng, X. Bu and P. Feng, Chem. Commun., 2011, 47, 11852 DOI: 10.1039/C1CC14836B

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