Application of a chiral metal–organic framework in enantioselective separation

Mohan Padmanaban; Philipp Müller; Christian Lieder; Kristina Gedrich; Ronny Grünker; Volodymyr Bon; Irena Senkovska; Sandra Baumgärtner; Sabine Opelt; Silvia Paasch; Eike Brunner; Frank Glorius; Elias Klemm; Stefan Kaskel

doi:10.1039/C1CC14893A

Application of a chiral metal–organic framework in enantioselective separation†

Mohan Padmanaban,^a Philipp Müller,^b Christian Lieder,^c Kristina Gedrich,^b Ronny Grünker,^b Volodymyr Bon,^b Irena Senkovska,^b Sandra Baumgärtner,^c Sabine Opelt,^c Silvia Paasch,^d Eike Brunner,^d Frank Glorius,*^a Elias Klemm*^c and Stefan Kaskel*^b

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* Corresponding authors

^a Westfälische Wilhelms-Universität, NRW Graduate School of Chemistry, Organisch-Chemisches Institut, Corrensstr. 40, 48149 Münster, Germany
E-mail: glorius@uni-muenster.de
Fax: +49 251 8333202
Tel: +49 251 8333248

^b Department of Inorganic Chemistry, Dresden University of Technology, Bergstr. 66, 01062 Dresden, Germany
E-mail: Stefan.Kaskel@chemie.tu-dresden.de
Fax: +49 351 46337287
Tel: +49 711 685 65590

^c Institute of Chemical Technology, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany
E-mail: elias.klemm@itc.uni-stuttgart.de
Fax: +49 711 68564065
Tel: +49 351 46334885

^d Department of Bioanalytical Chemistry, Dresden University of Technology, Bergstr. 66, 01062 Dresden, Germany
E-mail: eike.brunner@tu-dresden.de
Fax: +49 351 463 37188
Tel: +49 351 46332631

Abstract

A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal–organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported.

Chemical Communications

Application of a chiral metal–organic framework in enantioselective separation†

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Application of a chiral metal–organic framework in enantioselective separation

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