Issue 44, 2011
From the journal:

Chemical Communications

Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network†

Yasuhide Inokuma,a   Satoshi Nishiguchi,a   Koki Ikemotoa  and  Makoto Fujita*ab  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: mfujita@appchem.t.u-tokyo.ac.jp

b Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency (JST), Hongo, Bunkyo-ku, Tokyo, Japan

Abstract

A coordination network comprising 2-vinyltriphenylene was treated with AIBN at a high temperature, but the radical polymerization of the vinyl monomer was completely suppressed by spatial separation and otherwise hidden aerobic oxidation pathways are enhanced.

Graphical abstract: Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network

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Article information

DOI
https://doi.org/10.1039/C1CC15053G
Article type
Communication
Submitted
15 Aug 2011
Accepted
22 Sep 2011
First published
14 Oct 2011

Chem. Commun., 2011,47, 12113-12115

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Shedding light on hidden reaction pathways in radical polymerization by a porous coordination network

Y. Inokuma, S. Nishiguchi, K. Ikemoto and M. Fujita, Chem. Commun., 2011, 47, 12113 DOI: 10.1039/C1CC15053G

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