Issue 42, 2011
From the journal:

Chemical Communications

Reactivity studies of a corrole germanium hydride complex with aldehydes, olefins and alkyl halides†

Huayi Fang,a   Zhen Ling,a   Penelope J. Brothersb  and  Xuefeng Fu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn
Fax: +86 10-6275-1708
Tel: +86 10-6275-6035

b School of Chemical Sciences, The University of Auckland, Private Bag 92019, Auckland 1142, New Zealand

Abstract

The tris(pentafluorophenyl) corrole germanium hydride complex (TPFC)Ge-H was prepared by the reduction of (TPFC)Ge-OCH3 with NaBH4. The reactivity of (TPFC)Ge-H with series of aldehydes, olefins and alkyl halides to produce α-hydroxy alkyl and alkyl complexes was studied.

Graphical abstract: Reactivity studies of a corrole germanium hydride complex with aldehydes, olefins and alkyl halides

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Article information

DOI
https://doi.org/10.1039/C1CC15076F
Article type
Communication
Submitted
16 Aug 2011
Accepted
19 Sep 2011
First published
27 Sep 2011

Chem. Commun., 2011,47, 11677-11679

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Reactivity studies of a corrole germanium hydride complex with aldehydes, olefins and alkyl halides

H. Fang, Z. Ling, P. J. Brothers and X. Fu, Chem. Commun., 2011, 47, 11677 DOI: 10.1039/C1CC15076F

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