Issue 47, 2011
From the journal:

Chemical Communications

Unusual visible luminescence of aluminium polyoxocations in aqueous solution†

Zhaosheng Qian,‡*a   Congcong Chen,‡a   Jianrong Chen,a   Lichun Kong,a   Chen Wang,a   Jin Zhoua  and  Hui Feng*a  

* Corresponding authors

a College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, China
E-mail: qianzhaosheng@zjnu.cn, fenghui@zjnu.cn
Fax: +86-579-82282269
Tel: +86-579-82282269

Abstract

Identification of aluminium polyoxocations, MO4Al12(OH)24(H2O)127/8+ (M = Al, Ga and Ge) (K–MAl12) and Al30O8(OH)56(H2O)2618+ (Al30), by their luminescence is reported. The fluorescence behavior of K–Al13 has been found to differ with different metal ions and anions, implying a new discovery of a potential ion sensor.

Graphical abstract: Unusual visible luminescence of aluminium polyoxocations in aqueous solution

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Article information

DOI
https://doi.org/10.1039/C1CC15823F
Article type
Communication
Submitted
20 Sep 2011
Accepted
14 Oct 2011
First published
01 Nov 2011

Chem. Commun., 2011,47, 12652-12654

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Unusual visible luminescence of aluminium polyoxocations in aqueous solution

Z. Qian, C. Chen, J. Chen, L. Kong, C. Wang, J. Zhou and H. Feng, Chem. Commun., 2011, 47, 12652 DOI: 10.1039/C1CC15823F

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