Issue 47, 2011
From the journal:

Chemical Communications

Synthesis of diaryl ketonesvia a phosphine-free Fukuyama reaction†‡

Kamala Kunchithapatham,a   Chad C. Eichmana  and  James P. Stambuli*a  

* Corresponding authors

a Department of Chemistry, The Ohio State University, 100 West 18th Avenue, Ohio 43210, Columbus, United States
E-mail: stambuli@chemistry.ohio-state.edu

Abstract

The synthesis of unsymmetrical diaryl ketonesvia the Fukuyama coupling of thioesters and organozinc reagents is described. Typically, the synthesis of diaryl ketones using this methodology provides low yields. The simple complex, Pd(dba)2, was found to convert a variety of aryl thioesters to diaryl ketones in good yields.

Graphical abstract: Synthesis of diaryl ketonesvia a phosphine-free Fukuyama reaction

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Article information

DOI
https://doi.org/10.1039/C1CC16114H
Article type
Communication
Submitted
01 Oct 2011
Accepted
17 Oct 2011
First published
31 Oct 2011

Chem. Commun., 2011,47, 12679-12681

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Synthesis of diaryl ketonesvia a phosphine-free Fukuyama reaction

K. Kunchithapatham, C. C. Eichman and J. P. Stambuli, Chem. Commun., 2011, 47, 12679 DOI: 10.1039/C1CC16114H

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