Issue 9, 2011

Enantiocontrolled solid-state photodimerizations via a chiral sulfonamidecinnamic acid

Abstract

The supramolecular patterns of three polymorphs of a chiral sulfonamidecinnamic acid reveal components effectively organized into predetermined hydrogen-bonded dimers with favorable <3.8 Å olefin spacing for enantioselective single-crystal-to-single-crystal [2 + 2] photodimerization reactions.

Graphical abstract: Enantiocontrolled solid-state photodimerizations via a chiral sulfonamidecinnamic acid

Supplementary files

Article information

Article type
Communication
Submitted
10 Aug 2010
Accepted
24 Sep 2010
First published
08 Nov 2010

CrystEngComm, 2011,13, 3134-3137

Enantiocontrolled solid-state photodimerizations via a chiral sulfonamidecinnamic acid

K. A. Wheeler, J. D. Wiseman and R. C. Grove, CrystEngComm, 2011, 13, 3134 DOI: 10.1039/C0CE00516A

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