A novel green phosphorescent silver(I) coordination polymer with three-fold interpenetrated CdSO4-type net generated via in situ reaction

Yun Ling; Zhen-Xia Chen; Ya-Ming Zhou; Lin-Hong Weng; Dong-Yuan Zhao

doi:10.1039/C0CE00546K

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A novel green phosphorescent silver(i) coordination polymer with three-fold interpenetrated CdSO₄-type net generated via in situ reaction†

Yun Ling,^ab Zhen-Xia Chen,^ab Ya-Ming Zhou,*^a Lin-Hong Weng^a and Dong-Yuan Zhao*^ab

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* Corresponding authors

^a Department of Chemistry, Fudan University, Shanghai, China
E-mail: ymzhou@fudan.edu.cn
Fax: +86 21 65643925
Tel: +86 21 65642261

^b Laboratory of Advanced Materials, Fudan University, Shanghai, China
E-mail: dyzhao@fudan.edu.cn
Fax: +86 21 51630307
Tel: + 86 21 51630205

Abstract

A novel three-dimensional (3D) [Ag₃(dmtrz)₂(CN)]_n (1) with a three-fold interpenetrated CdSO₄-type net is in situ solvothermal synthesized, and influential factors in the in situ reaction are briefly discussed. The luminescent property studies reveal that 1 shows green phosphorescent emission upon excitation while other binary silver(I)-dmtrz compounds discussed in this paper only emit blue phosphorescence.

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Article information

DOI: https://doi.org/10.1039/C0CE00546K
Article type: Paper
Submitted: 18 Aug 2010
Accepted: 08 Nov 2010
First published: 18 Nov 2010

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CrystEngComm, 2011,13, 1504-1508

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A novel green phosphorescent silver(I) coordination polymer with three-fold interpenetrated CdSO₄-type net generated via in situ reaction

Y. Ling, Z. Chen, Y. Zhou, L. Weng and D. Zhao, CrystEngComm, 2011, 13, 1504 DOI: 10.1039/C0CE00546K

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