Issue 7, 2011

Metal–organic frameworks with rare topologies: lonsdaleite-type metal formates and their magnetic properties

Abstract

Single-crystal X-ray analysis revealed that isomorphous metal formates [M6(HCOO)12]·DEF (M = Mg2+, Fe2+, Co2+, Zn2+) have a framework with the lonsdaleite net, which is one of the rare topologies in metal–organic frameworks; iron and cobalt formates with metal sites bridged by single atoms showed dominant ferromagnetic and antiferromagnetic interactions, respectively.

Graphical abstract: Metal–organic frameworks with rare topologies: lonsdaleite-type metal formates and their magnetic properties

Supplementary files

Article information

Article type
Communication
Submitted
09 Jan 2011
Accepted
26 Jan 2011
First published
14 Feb 2011

CrystEngComm, 2011,13, 2197-2200

Metal–organic frameworks with rare topologies: lonsdaleite-type metal formates and their magnetic properties

H. Kim, Y. Sun, Y. Kim, T. Kajiwara, M. Yamashita and K. Kim, CrystEngComm, 2011, 13, 2197 DOI: 10.1039/C1CE05031A

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