Issue 21, 2011
From the journal:

CrystEngComm

Crystal engineering with 1,3,5-triaza-7-phosphaadamantane (PTA): first PTA-driven 3D metal–organic frameworks†

Alexander M. Kirillov,*a   Sabina W. Wieczorek,ab   M. Fátima C. Guedes da Silva,ac   Jerzy Sokolnicki,b   Piotr Smoleński*b  and  Armando J. L. Pombeiro*a  

* Corresponding authors

a Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, TU Lisbon, Avenida Rovisco Pais, Lisbon, Portugal
E-mail: kirillov@ist.utl.pt, pombeiro@ist.utl.pt
Fax: +351 218464455

b Faculty of Chemistry, University of Wrocław, ul. F. Joliot-Curie 14, Wroclaw, Poland
E-mail: psmol@wchuwr.pl

c Universidade Lusófona de Humanidades e Tecnologias, ULHT Lisbon, Av. do Campo Grande, 376, Lisbon, Portugal

Abstract

Two new luminescent silver–organic frameworks, [Ag2(μ2-bpca)(μ3-PTA)2]n·2nH2O (1) and [Ag4(μ4-pma)(μ2-PTA)2(μ3-PTA)2]n·8nH2O (2), have been easily generated from silver(I) oxide, PTA and aromatic carboxylic acids [biphenyl-4,4′-dicarboxylic (H2bpca) or pyromellitic (H4pma) acid], thus opening up the use of PTA as a versatile N,P-building block in crystal engineering of 3D networks. The topological analysis of 1 reveals a binodal 3,4-connected underlying net with the ins (InS) topology, while 2 represents a tetranodal 3,3,4,4-connected net with a new topology.

Graphical abstract: Crystal engineering with 1,3,5-triaza-7-phosphaadamantane (PTA): first PTA-driven 3D metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C1CE05612C
Article type
Communication
Submitted
23 May 2011
Accepted
24 Aug 2011
First published
08 Sep 2011

CrystEngComm, 2011,13, 6329-6333

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Crystal engineering with 1,3,5-triaza-7-phosphaadamantane (PTA): first PTA-driven 3D metal–organic frameworks

A. M. Kirillov, S. W. Wieczorek, M. F. C. Guedes da Silva, J. Sokolnicki, P. Smoleński and A. J. L. Pombeiro, CrystEngComm, 2011, 13, 6329 DOI: 10.1039/C1CE05612C

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