Issue 23, 2011
From the journal:

CrystEngComm

Rigid ferrocene–ferrocene dimer as a common building block in the crystal structures of ferrocene derivatives†

Goran A. Bogdanović*a  and  Sladjana B. Novakovića  

* Corresponding authors

a Vinča Institute of Nuclear Sciences, Laboratory of Theoretical Physics and Condensed Matter Physics, PO Box 522, Belgrade, Serbia
E-mail: goranb@vin.bg.ac.rs
Fax: +381 11 8065 829
Tel: +381 62 211 579

Abstract

The CSD study shows that 46.8% of ferrocene (Fc) containing crystal structures form a ferrocene–ferrocene dimer (FcD). In all those 2120 structures the FcD exhibits very similar geometry. An outstanding electrostatic complementarity between the Fc units within the dimer explains very frequent formation and constrained geometry of this building block.

Graphical abstract: Rigid ferrocene–ferrocene dimer as a common building block in the crystal structures of ferrocene derivatives

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Article information

DOI
https://doi.org/10.1039/C1CE06212C
Article type
Communication
Submitted
15 Sep 2011
Accepted
26 Sep 2011
First published
13 Oct 2011

CrystEngComm, 2011,13, 6930-6932

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Rigid ferrocene–ferrocene dimer as a common building block in the crystal structures of ferrocene derivatives

G. A. Bogdanović and S. B. Novaković, CrystEngComm, 2011, 13, 6930 DOI: 10.1039/C1CE06212C

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