Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf2N]

Lenaïc Lartigue; Rachel Pflieger; Sergey I. Nikitenko; Yannick Guari; Lorenzo Stievano; Moulay T. Sougrati; Joulia Larionova

doi:10.1039/C0CP01670E

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Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf₂N]†

Lenaïc Lartigue,^a Rachel Pflieger,^b Sergey I. Nikitenko,*^b Yannick Guari,*^a Lorenzo Stievano,^c Moulay T. Sougrati^c and Joulia Larionova^a

Author affiliations

* Corresponding authors

^a Institut Charles Gerhardt Montpellier, UMR 5253, Chimie Moléculaire et Organisation du Solide, Université Montpellier II, Place E. Bataillon, Montpellier Cx5, France
E-mail: yannick.guari@univ-montp2.fr
Fax: +33 4 67 14 38 52

^b Institut de Chimie Séparative de Marcoule, UMR 5257, Centre de Marcoule, BP 17171, F-30207 Bagnols sur Cèze, France
E-mail: serguei.nikitenko@cea.fr
Fax: +33 4 67 79 76 11

^c Institut Charles Gerhardt Montpellier, UMR 5253, Agrégats, Interfaces et Matériaux pour l'Energie, Université Montpellier II, Place E. Bataillon, Montpellier Cx5, France

Abstract

The autocatalytic sonochemical reaction of Fe(CO)₅ decomposition in [BuMeIm][Tf₂N] provides iron nanoparticles in higher yields than in tetralin. Such a difference is explained by the higher decomposition of the intermediate Fe₃(CO)₁₂ according to the two-sites model of the sonochemical reactions and the specific properties of the ionic liquid.

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Article information

DOI: https://doi.org/10.1039/C0CP01670E
Article type: Communication
Submitted: 01 Sep 2010
Accepted: 08 Nov 2010
First published: 10 Dec 2010

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Phys. Chem. Chem. Phys., 2011,13, 2111-2113

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Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf₂N]

L. Lartigue, R. Pflieger, S. I. Nikitenko, Y. Guari, L. Stievano, M. T. Sougrati and J. Larionova, Phys. Chem. Chem. Phys., 2011, 13, 2111 DOI: 10.1039/C0CP01670E

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