Issue 41, 2011
From the journal:

Dalton Transactions

Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels†

Ja-Min Gu,a   Wan-Seok Kima  and  Seong Huh*a  

* Corresponding authors

a Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin, Korea
E-mail: shuh@hufs.ac.kr
Fax: 82 31 330 4566
Tel: 82 31 330 4522

Abstract

Lewis basic DABCO-functionalized 3D-like metal–organic framework, Zn-MOF, catalyzes nitroaldol (Henry) reaction of 4-nitrobenzaldehyde with nitroalkanes in a size-dependent manner. Small nitroalkanes give rise to higher conversion than larger ones. This MOF-based heterogeneous catalyst is very robust and can be recycled several times without losing its activity.

Graphical abstract: Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels

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Article information

DOI
https://doi.org/10.1039/C1DT11274K
Article type
Communication
Submitted
05 Jul 2011
Accepted
23 Aug 2011
First published
20 Sep 2011

Dalton Trans., 2011,40, 10826-10829

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Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels

J. Gu, W. Kim and S. Huh, Dalton Trans., 2011, 40, 10826 DOI: 10.1039/C1DT11274K

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