The neutral complex [PtCl(PyDT)]5 (PyDT = (CH2)4NCS2−) represents the first example of a Pt5 metallacycle. This unique architecture based on chiral S-bridged PtII monomers was prepared by thermal degradation of the reaction product of PtCl2 and a pyrrolidinedithioester.
![Graphical abstract: Unique Pt5 metallacycle: [PtIICl(pyrrolidinedithiocarbamate)]5](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C1DT11475A&imageInfo.ImageIdentifier.Year=2011)
D. Montagner and P. J. Sanz Miguel, Dalton Trans., 2011, 40, 10809 DOI: 10.1039/C1DT11475A
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