Volume 152, 2011
From the journal:

Faraday Discussions

Theoretical insights into the superior activity of gold catalysts and reactions of organogold intermediates with electrophiles

A. Stephen K. Hashmi,*a   Markus Pernpointnera  and  Max M. Hansmanna  

* Corresponding authors

a Universität Heidelberg, Organisch-Chemisches Institut, Im Neuenheimer Feld 270, Heidelberg, Germany
E-mail: hashmi@hashmi.de
Fax: +49-6221-544205
Tel: +49-6221-548413

Abstract

Three fundamental steps of homogeneous gold catalysis, the activiation of substrates by coordination to gold, the protodeauration after the nucleophilic addition and the transmetalation to palladium in palladium-catalysed C-C bond forming reactions using organogold intermediates have been studied and discussed in detail.

  • This article is part of the themed collection: Gold
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Article information

DOI
https://doi.org/10.1039/C1FD00029B
Article type
Paper
Submitted
02 Mar 2011
Accepted
05 Apr 2011
First published
27 Jul 2011

Faraday Discuss., 2011,152, 179-184

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Theoretical insights into the superior activity of gold catalysts and reactions of organogold intermediates with electrophiles

A. S. K. Hashmi, M. Pernpointner and M. M. Hansmann, Faraday Discuss., 2011, 152, 179 DOI: 10.1039/C1FD00029B

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