TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations by operando-XRD and Mössbauer techniques

Abstract

We report the electrochemical study of TiSnSb towards Li, as a negative electrode for Li-ion batteries. TiSnSb can reversibly take up more than 5 lithiums per formula unit leading to reversible capacities of 540 mA h g⁻¹ and 4070 mA h cm⁻³ at 2 C rate. From complementary operandoXRD and Mössbauer spectroscopy measurements, it was shown that during the first discharge the TiSnSb undergoes a conversion process leading simultaneously to the formation of Li–Sb and Li–Sn alloys. At the end of the discharge, Li₃Sb and Li₇Sn₂ were identified. Once the first discharge is achieved, both phases were shown to form Ti–Sn or Ti–Sb or Ti–Sn–Sb nanocomposites. The cycling performance of TiSnSb was shown to be excellent with maintaining 90% of the specific capacity during 60 cycles at 2 C rate. The good electrochemical performance of TiSnSb (compared to Sn and Sb) seems to be a consequence of the presence of the non-active metal. The comparative study of Ti/Sn/Sb composite demonstrated that the structural feature of the pristine material clearly impacts both the mechanism involved during the cycling and the corresponding performance.