Issue 2, 2011
From the journal:

Organic & Biomolecular Chemistry

2-Phenoxyethanol derived diselenide and related compounds; synthesis of a seven-membered seleninate ester†

Santosh K. Tripathi,a   Sagar Sharma,a   Harkesh B. Singh*a  and  Ray J. Butcherb  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, India
E-mail: chhbsia@chem.iitb.ac.in
Fax: +91 022 2572 3480
Tel: +91 022 2576 7190

b Department of Chemistry, Howard University, USA

Abstract

Syntheses of several diorganodiselenides and, in particular, a seven-membered cyclic seleninate ester derived from 2-phenoxyethanol are described. The seleninate ester was obtained from allyl (2-(2-hydroxyethoxy)phenyl) selenide through a series of oxidation and [2,3] sigmatropic rearrangement steps. The ester exhibits good GPx-like activity in the coupled reductase assay.

Graphical abstract: 2-Phenoxyethanol derived diselenide and related compounds; synthesis of a seven-membered seleninate ester

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Article information

DOI
https://doi.org/10.1039/C0OB00038H
Article type
Paper
Submitted
23 Apr 2010
Accepted
16 Sep 2010
First published
04 Nov 2010

Org. Biomol. Chem., 2011,9, 581-587

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2-Phenoxyethanol derived diselenide and related compounds; synthesis of a seven-membered seleninate ester

S. K. Tripathi, S. Sharma, H. B. Singh and R. J. Butcher, Org. Biomol. Chem., 2011, 9, 581 DOI: 10.1039/C0OB00038H

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