Issue 6, 2011
From the journal:

Organic & Biomolecular Chemistry

Ruthenium(iii)-catalysed phenylselenylation of allyl acetates by diphenyl diselenide and indium(i) bromide in neat: isolation and identification of intermediate†

Amit Sahaa  and  Brindaban C. Ranu*a  

* Corresponding authors

a Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, India
E-mail: ocbcr@iacs.res.in
Fax: +91 33 24732805

Abstract

A fast and efficient phenylselenylation of allyl acetates by diphenyl diselenide and indium(I) bromide has been achieved in neat under the catalysis of Ru(acac)3. The intermediate complex of diphenyl diselenide and indium has been isolated and identified as a polymeric pentacoordinated In(III) selenolate complex, [In(SePh)3]n.

Graphical abstract: Ruthenium(iii)-catalysed phenylselenylation of allyl acetates by diphenyl diselenide and indium(i) bromide in neat: isolation and identification of intermediate

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Article information

DOI
https://doi.org/10.1039/C0OB00317D
Article type
Paper
Submitted
25 Jun 2010
Accepted
24 Nov 2010
First published
25 Nov 2010

Org. Biomol. Chem., 2011,9, 1763-1767

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Ruthenium(III)-catalysed phenylselenylation of allyl acetates by diphenyl diselenide and indium(I) bromide in neat: isolation and identification of intermediate

A. Saha and B. C. Ranu, Org. Biomol. Chem., 2011, 9, 1763 DOI: 10.1039/C0OB00317D

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