Issue 3, 2011
From the journal:

Organic & Biomolecular Chemistry

Oxidoreductive coupling of thiols with aryl halides catalyzed by copper on iron†

Szabolcs Kovácsa  and  Zoltán Novák*a  

* Corresponding authors

a Department of Organic Chemistry, Institute of Chemistry, Eötvös Loránd University, Pázmány Péter stny. 1/a, Budapest, Hungary
E-mail: novakz@elte.hu
Fax: +36-1-372-2909
Tel: +36-1-372-2500 ext. 1610

Abstract

Synthesis and utilization of a simple copper on iron catalyst in the coupling of aryl halides with thiols through disulfide intermediate is reported. The iron support of copper catalyst ensures reductive media for the coupling, allows easy removal of the metals by outer magnetic field and enables the recycling of the catalyst.

Graphical abstract: Oxidoreductive coupling of thiols with aryl halides catalyzed by copper on iron

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Article information

DOI
https://doi.org/10.1039/C0OB00397B
Article type
Paper
Submitted
07 Jul 2010
Accepted
01 Oct 2010
First published
16 Nov 2010

Org. Biomol. Chem., 2011,9, 711-716

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Oxidoreductive coupling of thiols with aryl halides catalyzed by copper on iron

S. Kovács and Z. Novák, Org. Biomol. Chem., 2011, 9, 711 DOI: 10.1039/C0OB00397B

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