Issue 16, 2011
From the journal:

Organic & Biomolecular Chemistry

Ligand-free palladium-catalyzed intramolecular Heck reaction of secondary benzylic bromides†

Wei Zhou,a   Guanghui An,a   Guangqian Zhang,a   Jianlin Han*a  and  Yi Pan*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China
E-mail: hanjl@nju.edu.cn, yipan@nju.edu.cn
Fax: +86-25-83593153

Abstract

A facile ligand-free palladium-catalyzed intramolecular Heck reaction of β-hydrogen-containing secondary benzylic bromides was developed, which affords pyrroline derivatives with good regioselectivities.

Graphical abstract: Ligand-free palladium-catalyzed intramolecular Heck reaction of secondary benzylic bromides

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Article information

DOI
https://doi.org/10.1039/C1OB05231D
Article type
Paper
Submitted
14 Feb 2011
Accepted
26 May 2011
First published
27 May 2011

Org. Biomol. Chem., 2011,9, 5833-5837

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Ligand-free palladium-catalyzed intramolecular Heck reaction of secondary benzylic bromides

W. Zhou, G. An, G. Zhang, J. Han and Y. Pan, Org. Biomol. Chem., 2011, 9, 5833 DOI: 10.1039/C1OB05231D

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