Issue 16, 2011
From the journal:

Organic & Biomolecular Chemistry

A synergistic approach to polycyclics via a strategic utilization of Claisen rearrangement and olefinmetathesis

Sambasivarao Kotha,*a   Nimita G. Krishna,a   Somnath Halder†a  and  Shilpi Misraa  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai, India
E-mail: srk@chem.iitb.ac.in
Fax: +91-22-2572 3480

Abstract

Olefin metathesis promoted by a well-defined metal carbene complex has evolved into an efficient method for the construction of a broad range of carbocyclic and heterocyclic rings of varying size. The synthetic potential of the olefin metathesis has been further increased by combining various other C–C bond forming processes either in tandem or in sequence. Herein, application of Claisen rearrangement and olefin metathesis to prepare various intricate and/or biologically important targets has been described.

Graphical abstract: A synergistic approach to polycyclics via a strategic utilization of Claisen rearrangement and olefin metathesis

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Article information

DOI
https://doi.org/10.1039/C1OB05413A
Article type
Perspective
Submitted
16 Mar 2011
Accepted
10 May 2011
First published
07 Jun 2011

Org. Biomol. Chem., 2011,9, 5597-5624

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A synergistic approach to polycyclics via a strategic utilization of Claisen rearrangement and olefin metathesis

S. Kotha, N. G. Krishna, S. Halder and S. Misra, Org. Biomol. Chem., 2011, 9, 5597 DOI: 10.1039/C1OB05413A

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