Issue 21, 2011
From the journal:

Organic & Biomolecular Chemistry

Macrocyclic receptor for pertechnetate and perrhenate anions†

Grigory V. Kolesnikov,ab   Konstantin E. German,c   Gayane Kirakosyan,c   Ivan G. Tananaev,c   Yuri A. Ustynyuk,a   Victor N. Khrustalevb  and  Evgeny A. Katayev*d  

* Corresponding authors

a Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie gory 1/3, Moscow, Russian Federation

b A.N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences, Vavilov st., 28, Moscow, Russian Federation

c A.N. Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences, Leninskiy pr. 31, Moscow, Russian Federation

d Institut für Organische Chemie, Universität Regensburg, Universitätsstr. 31, 93040 Regensburg, Germany
E-mail: evgeny.katayev@chemie.uni-regensburg.de
Tel: +49 941 9434628

Abstract

The design and synthesis of a neutral macrocyclic host that is capable of perrhenate and pertechnetate recognition is described. The anion affinities and underlying coordination modes were estimated by several experimental and theoretical methods including a new technique—reverse 99Tc NMR titration.

Graphical abstract: Macrocyclic receptor for pertechnetate and perrhenate anions

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Article information

DOI
https://doi.org/10.1039/C1OB05873H
Article type
Paper
Submitted
01 Jun 2011
Accepted
05 Aug 2011
First published
05 Aug 2011

Org. Biomol. Chem., 2011,9, 7358-7364

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Macrocyclic receptor for pertechnetate and perrhenate anions

G. V. Kolesnikov, K. E. German, G. Kirakosyan, I. G. Tananaev, Y. A. Ustynyuk, V. N. Khrustalev and E. A. Katayev, Org. Biomol. Chem., 2011, 9, 7358 DOI: 10.1039/C1OB05873H

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