Issue 10, 2012
From the journal:

Chemical Communications

Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines†

Luca Bernardi,*a   Eugenio Indrigo,a   Salvatore Pollicinoa  and  Alfredo Riccia  

* Corresponding authors

a Department of Organic Chemistry “A. Mangini”, University of Bologna, V. Risorgimento 4, 40136 Bologna, Italy
E-mail: luca.bernardi2@.unibo.it
Fax: +39 051 2093654
Tel: +39 0512093631

Abstract

A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.

Graphical abstract: Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

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Article information

DOI
https://doi.org/10.1039/C0CC05777K
Article type
Communication
Submitted
24 Dec 2010
Accepted
21 Mar 2011
First published
11 Apr 2011

Chem. Commun., 2012,48, 1428-1430

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Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines

L. Bernardi, E. Indrigo, S. Pollicino and A. Ricci, Chem. Commun., 2012, 48, 1428 DOI: 10.1039/C0CC05777K

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