Catalytic        hydroboration by an imido-hydrido complex of Mo(IV)

Andrey Y. Khalimon; Philip Farha; Lyudmila G. Kuzmina; Georgii I. Nikonov

doi:10.1039/C1CC14508H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Catalytic hydroboration by an imido-hydrido complex of Mo(iv)†

Andrey Y. Khalimon,^a Philip Farha,^a Lyudmila G. Kuzmina^b and Georgii I. Nikonov*^a

Author affiliations

* Corresponding authors

^a Chemistry Department, Brock University, 500 Glenridge Ave., St. Catharines, ON, Canada
E-mail: gnikonov@brocku.ca
Tel: +1 905 6885550, ext 3350

^b Kurnakov Institute of General and Inorganic Chemistry RAS, Leninskii Prosp. 31, Moscow, Russia
E-mail: kuzmina@igic.ras.ru

Abstract

The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe₃)₃ catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH₂N(BCat)₂. The latter species easily undergoes chemoselective coupling with aldehydes R′C(O)H to yield imines RCH₂N [double bond, length as m-dash] C(H)R′.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C1CC14508H
Article type: Communication
Submitted: 24 Jul 2011
Accepted: 25 Oct 2011
First published: 11 Nov 2011

Download Citation

Chem. Commun., 2012,48, 455-457

Permissions

Request permissions

Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

A. Y. Khalimon, P. Farha, L. G. Kuzmina and G. I. Nikonov, Chem. Commun., 2012, 48, 455 DOI: 10.1039/C1CC14508H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications