Issue 1, 2012
From the journal:

Chemical Communications

Melting point suppression in new lanthanoid(iii) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study†

Anthony S. R. Chesman,ab   Mei Yang,a   Bert Mallick,a   Tamsyn M. Ross,b   Ian A. Gass,b   Glen B. Deacon,b   Stuart R. Batten*b  and  Anja-Verena Mudring*a  

* Corresponding authors

a Anorganische Chemie I – Festkörperchemie und Materialien, Ruhr-Universität Bochum, 44780 Bochum, Germany
E-mail: anja.mudring@rub.de

b School of Chemistry, Monash University, Clayton, Australia
E-mail: stuart.batten@monash.edu

Abstract

The complexes (N4444)3[Ln(dcnm)6] (Ln = La–Nd, Sm; N4444 = tetrabutylammonium) display a decrease in the melting point upon fast cooling from a melt, which is shown by in situsynchrotron based X-ray powder diffraction to be due to the formation of a second, less thermodynamically stable, polymorph.

Graphical abstract: Melting point suppression in new lanthanoid(iii) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study

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Article information

DOI
https://doi.org/10.1039/C1CC14744G
Article type
Communication
Submitted
01 Aug 2011
Accepted
05 Oct 2011
First published
03 Nov 2011

Chem. Commun., 2012,48, 124-126

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Melting point suppression in new lanthanoid(III) ionic liquids by trapping of kinetic polymorphs: an in situsynchrotron powder diffraction study

A. S. R. Chesman, M. Yang, B. Mallick, T. M. Ross, I. A. Gass, G. B. Deacon, S. R. Batten and A. Mudring, Chem. Commun., 2012, 48, 124 DOI: 10.1039/C1CC14744G

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