Issue 2, 2012
From the journal:

Chemical Communications

Stepwise syntheses of tri- and tetraphosphaporphyrinogens†

Duncan Carmichael,*a   Aurélie Escalle-Lewis,a   Gilles Frison,b   Xavier Le Goffa  and  Eric Mullera  

* Corresponding authors

a Laboratoire “Hétéroéléments et Coordination”, Ecole Polytechnique and CNRS, 91128 Palaiseau cedex, France
E-mail: Duncan.Carmichael@polytechnique.edu
Fax: (+) 33 1 69 33 44 40

b Laboratoire des Mécanismes Réactionnels, Ecole Polytechnique and CNRS, 91128 Palaiseau cedex, France
Fax: (+) 33 1 69 33 48 03

Abstract

A double ring-expansion methodology allows the stepwise synthesis of tri- and tetra-phosphaporhyrinogens. Structural and calculational methods reveal extended delocalisation about their phospholide centres.

Graphical abstract: Stepwise syntheses of tri- and tetraphosphaporphyrinogens

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Article information

DOI
https://doi.org/10.1039/C1CC15421D
Article type
Communication
Submitted
31 Aug 2011
Accepted
31 Oct 2011
First published
17 Nov 2011

Chem. Commun., 2012,48, 302-304

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Stepwise syntheses of tri- and tetraphosphaporphyrinogens

D. Carmichael, A. Escalle-Lewis, G. Frison, X. L. Goff and E. Muller, Chem. Commun., 2012, 48, 302 DOI: 10.1039/C1CC15421D

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