Issue 8, 2012
From the journal:

Chemical Communications

Hybrid charged heterometallic Pt–Ir complexes: tailoring excited states by taking the best of both worlds†

Ahmed M. Soliman,a   Daniel Fortin,a   Pierre D. Harvey*a  and  Eli Zysman-Colman*a  

* Corresponding authors

a Département de Chimie, Université de Sherbrooke and the Centre Québécois sur les Matériaux Fonctionnels, 2500 Boul. de l'Université, Sherbrooke, QC, Canada
E-mail: pierre.harvey@uhsebrooke.ca, eli.zysman-colman@usherbrooke.ca
Fax: +1 819-821-8017

Abstract

The C[triple bond, length as m-dash]C-linkage of Pt(PR3)2(C[triple bond, length as m-dash]CAr)2 with (C⁁N)2Ir(N⁁N)+ (C⁁N = 2-phenylpyridine; N⁁N = bipyridyl) leads to hetero-bi- and trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] → [Ir] charge transfer excited state.

Graphical abstract: Hybrid charged heterometallic Pt–Ir complexes: tailoring excited states by taking the best of both worlds

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Article information

DOI
https://doi.org/10.1039/C1CC15507E
Article type
Communication
Submitted
06 Sep 2011
Accepted
01 Oct 2011
First published
12 Dec 2011

Chem. Commun., 2012,48, 1120-1122

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Hybrid charged heterometallic Pt–Ir complexes: tailoring excited states by taking the best of both worlds

A. M. Soliman, D. Fortin, P. D. Harvey and E. Zysman-Colman, Chem. Commun., 2012, 48, 1120 DOI: 10.1039/C1CC15507E

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