Issue 9, 2012
From the journal:

Chemical Communications

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state†

Xikui Fang,*a   Paul Kögerler,*b   Manfred Speldrich,b   Helmut Schilderb  and  Marshall Lubana  

* Corresponding authors

a Ames Laboratory, US DOE and Department of Physics and Astronomy, Iowa State University, Ames, USA
E-mail: xfang@ameslab.gov
Fax: +1 515-294-0689
Tel: +1 515-294-7505

b Institute of Inorganic Chemistry, RWTH Aachen University, D-52074 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de
Fax: +49 241 8092642

Abstract

Ligand modification transforms a polyoxometalate-anchored cubane-type [MnIII3MnIVO4] core into a centrosymmetric [MnIII6MnIVO8] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn4O4] cubane-based single-molecule magnets.

Graphical abstract: A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

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Article information

DOI
https://doi.org/10.1039/C1CC15520B
Article type
Communication
Submitted
06 Sep 2011
Accepted
28 Oct 2011
First published
18 Nov 2011

Chem. Commun., 2012,48, 1218-1220

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A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

X. Fang, P. Kögerler, M. Speldrich, H. Schilder and M. Luban, Chem. Commun., 2012, 48, 1218 DOI: 10.1039/C1CC15520B

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