Issue 1, 2012
From the journal:

Chemical Communications

Chemoselective conversion of α-unbranched aldehydes to amides, esters, and carboxylic acids by NHC-catalysis†

Satoru Kuwano,a   Shingo Harada,a   Raphaël Orieza  and  Ken-ichi Yamada*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: yamak@pharm.kyoto-u.ac.jp
Fax: +81 75 753 4604
Tel: +81 75 753 4573

Abstract

Depending on the N-heterocyclic carbene catalyst utilized, α-unbranched aldehydes selectively provided amides, esters, or carboxylic acids through oxidation by NCS. The α-unbranched aldehyde underwent these reactions chemoselectively in the presence of an aromatic or α-branched aldehyde.

Graphical abstract: Chemoselective conversion of α-unbranched aldehydes to amides, esters, and carboxylic acids by NHC-catalysis

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Article information

DOI
https://doi.org/10.1039/C1CC15539C
Article type
Communication
Submitted
07 Sep 2011
Accepted
18 Oct 2011
First published
07 Nov 2011

Chem. Commun., 2012,48, 145-147

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Chemoselective conversion of α-unbranched aldehydes to amides, esters, and carboxylic acids by NHC-catalysis

S. Kuwano, S. Harada, R. Oriez and K. Yamada, Chem. Commun., 2012, 48, 145 DOI: 10.1039/C1CC15539C

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