Issue 5, 2012
From the journal:

Chemical Communications

A new efficient ironcatalyst for olefinepoxidation with hydrogen peroxide†

Elena A. Mikhalyova,ab   Olga V. Makhlynets,a   Taryn D. Palluccio,a   Alexander S. Filatovc  and  Elena V. Rybak-Akimova*a  

* Corresponding authors

a Department of Chemistry, Tufts University, 62 Talbot Avenue, Medford, Massachusetts 02155, USA
E-mail: erybakak@tufts.edu
Fax: +1-6176273443
Tel: +1-6176273413

b L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of the Ukraine, Prospekt Nauki 31, Kiev, Ukraine

c Department of Chemistry, University at Albany, 1400 Washington Avenue, Albany, New York 12222, USA
E-mail: afilatov@albany.edu
Fax: +1-5184423462
Tel: +1-5184424428

Abstract

A new aminopyridine ligand derived from bipiperidine (the product of full reduction of bipyridine, bipy) coordinates to iron(II) in a cis-α fashion, yielding a new selective catalyst for olefin epoxidation with H2O2 under limiting substrate conditions.

Graphical abstract: A new efficient iron catalyst for olefin epoxidation with hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/C1CC15935F
Article type
Communication
Submitted
23 Sep 2011
Accepted
15 Nov 2011
First published
01 Dec 2011

Chem. Commun., 2012,48, 687-689

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A new efficient iron catalyst for olefin epoxidation with hydrogen peroxide

E. A. Mikhalyova, O. V. Makhlynets, T. D. Palluccio, A. S. Filatov and E. V. Rybak-Akimova, Chem. Commun., 2012, 48, 687 DOI: 10.1039/C1CC15935F

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