Issue 7, 2012
From the journal:

Chemical Communications

The coordination and polymerisation of cyclic 1,3-dienes by gold(i) cations†

Rajashekharayya A. Sanguramath,a   Sanjib K. Patra,a   Michael Greena  and  Christopher A. Russella  

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: Chris.Russell@bris.ac.uk
Fax: +44 (0)117 929 0509
Tel: +44 (0)117 928 7599

Abstract

Cyclopentadiene and 1,3-cyclohexadiene are readily polymerised by [LAu][X]. With specific ancillary ligands polymerisation was suppressed and a molecular species involving an Au(I) cation η2-bonding CpH was isolated and whose structure was probed in both the solid state and in solution.

Graphical abstract: The coordination and polymerisation of cyclic 1,3-dienes by gold(i) cations

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Article information

DOI
https://doi.org/10.1039/C1CC16193H
Article type
Communication
Submitted
05 Oct 2011
Accepted
21 Nov 2011
First published
08 Dec 2011

Chem. Commun., 2012,48, 1060-1062

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The coordination and polymerisation of cyclic 1,3-dienes by gold(I) cations

R. A. Sanguramath, S. K. Patra, M. Green and C. A. Russell, Chem. Commun., 2012, 48, 1060 DOI: 10.1039/C1CC16193H

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