Issue 14, 2012
From the journal:

Chemical Communications

Anomalous thermal transition and crystallization of ionic liquids confined in graphene multilayers†

Jinkyu Im,a   Sung Dae Cho,b   Min Hye Kim,b   Young Mee Jung,c   Hoon Sik Kim*a  and  Ho Seok Park*b  

* Corresponding authors

a Department of Chemistry and Research Institute of Basic Sciences, Kyung Hee University, 1 Hoegidong, Dongdamoongu, Seoul, Republic of Korea

b Department of Chemical Engineering, College of Engineering, Kyung Hee University, 1 Seochon-dong, Giheung-gu, Youngin-si, Republic of Korea
E-mail: phs0727@khu.ac.kr

c Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University, Republic of Korea

Abstract

Anomalous thermal transition and crystallization behaviors of three room temperature ionic liquids (RTILs) in graphene multilayers (GMLs), in a different manner to bulk RTILs, occurred due to the molecular orientation of the confined system triggered by the complex π–π stacking and hydrogen bonding interactions.

Graphical abstract: Anomalous thermal transition and crystallization of ionic liquids confined in graphene multilayers

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Article information

DOI
https://doi.org/10.1039/C2CC16367E
Article type
Communication
Submitted
13 Oct 2011
Accepted
12 Dec 2011
First published
13 Dec 2011

Chem. Commun., 2012,48, 2015-2017

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Anomalous thermal transition and crystallization of ionic liquids confined in graphene multilayers

J. Im, S. D. Cho, M. H. Kim, Y. M. Jung, H. S. Kim and H. S. Park, Chem. Commun., 2012, 48, 2015 DOI: 10.1039/C2CC16367E

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