Issue 33, 2012
From the journal:

Chemical Communications

Slow magnetic relaxation in a pseudotetrahedral cobalt(ii) complex with easy-plane anisotropy†

Joseph M. Zadrozny,a   Junjie Liu,bc   Nicholas A. Piro,a   Christopher J. Chang,*ad   Stephen Hill*b  and  Jeffrey R. Long*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, USA
E-mail: chrischang@berkeley.edu, jrlong@berkeley.edu

b National High Magnetic Field Laboratory, Tallahassee, Florida, USA
E-mail: shill@magnet.fsu.edu

c Department of Physics, University of Florida, Gainesville, USA

d Chemical Sciences Division, Lawrence Berkeley National Laboratory and Howard Hughes Medical Institute, University of California, Berkeley, California, USA

Abstract

A pseudotetrahedral cobalt(II) complex with a positive axial zero-field splitting parameter of D = 12.7 cm−1, as determined by high-field EPR spectroscopy, is shown to exhibit slow magnetic relaxation under an applied dc field.

Graphical abstract: Slow magnetic relaxation in a pseudotetrahedral cobalt(ii) complex with easy-plane anisotropy

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Article information

DOI
https://doi.org/10.1039/C2CC16430B
Article type
Communication
Submitted
16 Oct 2011
Accepted
01 Dec 2011
First published
02 Dec 2011

Chem. Commun., 2012,48, 3927-3929

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Slow magnetic relaxation in a pseudotetrahedral cobalt(II) complex with easy-plane anisotropy

J. M. Zadrozny, J. Liu, N. A. Piro, C. J. Chang, S. Hill and J. R. Long, Chem. Commun., 2012, 48, 3927 DOI: 10.1039/C2CC16430B

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