Issue 16, 2012
From the journal:

Chemical Communications

Palladium-catalyzed allylic C–H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role†

Tao Xiong,a   Yan Li,*a   Lujia Mao,a   Qian Zhang‡a  and  Qian Zhang*a  

* Corresponding authors

a Department of Chemistry, Northeast Normal University, Changchun, China
E-mail: liy078@nenu.edu.cn, zhangq651@nenu.edu.cn
Fax: +86-431-85099759

Abstract

A new palladium-catalyzed highly regioselective allylic C–H amination of alkenes with NFSI in the presence of a catalytic amount of water was developed and successfully expanded to Selectfluor-mediated palladium-catalyzed aminations of alkenes with N-tosylcarbamates in water at room temperature.

Graphical abstract: Palladium-catalyzed allylic C–H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role

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Article information

DOI
https://doi.org/10.1039/C2CC16720D
Article type
Communication
Submitted
30 Oct 2011
Accepted
22 Dec 2011
First published
17 Jan 2012

Chem. Commun., 2012,48, 2246-2248

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Palladium-catalyzed allylic C–H amination of alkenes with N-fluorodibenzenesulfonimide: water plays an important role

T. Xiong, Y. Li, L. Mao, Q. Zhang and Q. Zhang, Chem. Commun., 2012, 48, 2246 DOI: 10.1039/C2CC16720D

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