Issue 18, 2012
From the journal:

Chemical Communications

One-pot synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines using supported gold and base as catalysts†

Søren Kegnæs,a   Jerrik Mielby,a   Uffe V. Mentzel,a   Thomas Jensen,a   Peter Fristrupa  and  Anders Riisager*a  

* Corresponding authors

a Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark, Building 207, 2800 Kgs. Lyngby, Denmark
E-mail: ar@kemi.dtu.dk

Abstract

Synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with aminesvia intermediate formation of methyl esters is highly efficient and selective when using a catalytic system comprised of supported gold nanoparticles and added base in methanol.

Graphical abstract: One-pot synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines using supported gold and base as catalysts

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Article information

DOI
https://doi.org/10.1039/C2CC16768A
Article type
Communication
Submitted
01 Nov 2011
Accepted
10 Jan 2012
First published
25 Jan 2012

Chem. Commun., 2012,48, 2427-2429

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One-pot synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines using supported gold and base as catalysts

S. Kegnæs, J. Mielby, U. V. Mentzel, T. Jensen, P. Fristrup and A. Riisager, Chem. Commun., 2012, 48, 2427 DOI: 10.1039/C2CC16768A

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