Issue 14, 2012
From the journal:

Chemical Communications

Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts†

Hongli Liu,a   Biaolin Yin,a   Zhiqiang Gao,a   Yingwei Li*a  and  Huanfeng Jiang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: liyw@scut.edu.cn

Abstract

A novel heterogeneous catalysis system using metal–organic frameworks as catalyst demonstrated excellent chemo- and regioselectivity for the direct arylation of unactivated arenes with aryl iodides/bromides without the assistance of any transition metals.

Graphical abstract: Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts

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Article information

DOI
https://doi.org/10.1039/C2CC16790E
Article type
Communication
Submitted
02 Nov 2011
Accepted
15 Dec 2011
First published
09 Jan 2012

Chem. Commun., 2012,48, 2033-2035

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Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts

H. Liu, B. Yin, Z. Gao, Y. Li and H. Jiang, Chem. Commun., 2012, 48, 2033 DOI: 10.1039/C2CC16790E

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