Issue 12, 2012
From the journal:

Chemical Communications

Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5†

Tuan T. Dang,a   Yinghuai Zhu,a   Subhash C. Ghosh,a   Anqi Chen,a   Christina L. L. Chaia  and  Abdul M. Seayad*a  

* Corresponding authors

a Institute of Chemical and Engineering Sciences (ICES), 8 Biomedical Grove, #07-01 Neuros, Singapore
E-mail: abdul_seayad@ices.a-star.edu.sg
Fax: +65-64642102
Tel: +65-67998527

Abstract

An efficient amide synthesis by atmospheric pressure aminocarbonylation using palladium nanoparticles supported on MOF-5 is reported. Interestingly, only 0.5 wt% palladium loading was required to achieve high yields. The catalyst is recyclable and offers negligible palladium leaching.

Graphical abstract: Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5

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Article information

DOI
https://doi.org/10.1039/C2CC16808A
Article type
Communication
Submitted
03 Nov 2011
Accepted
02 Dec 2011
First published
02 Dec 2011

Chem. Commun., 2012,48, 1805-1807

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Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5

T. T. Dang, Y. Zhu, S. C. Ghosh, A. Chen, C. L. L. Chai and A. M. Seayad, Chem. Commun., 2012, 48, 1805 DOI: 10.1039/C2CC16808A

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