Issue 15, 2012

Unusual group migration and C(sp3)–H activation leading to stable metallacycles in the reactions of Cp*IrS2C2B10H10 and aryl azides

Abstract

The thermal or photochemical reactions of Cp*IrS2C2B10H10 (1) and aryl azides lead to C–C coupling via C(sp3)–H activation in 2 as well as the formation of C–S bonds and new-type SSN pincer ligands in 3–8 through ortho-substituted electron-withdrawing group migration over an aryl ring.

Graphical abstract: Unusual group migration and C(sp3)–H activation leading to stable metallacycles in the reactions of Cp*IrS2C2B10H10 and aryl azides

Supplementary files

Article information

Article type
Communication
Submitted
09 Nov 2011
Accepted
15 Dec 2011
First published
13 Jan 2012

Chem. Commun., 2012,48, 2152-2154

Unusual group migration and C(sp3)–H activation leading to stable metallacycles in the reactions of Cp*IrS2C2B10H10 and aryl azides

W. Zhong, M. Xie, Q. Jiang, Y. Li and H. Yan, Chem. Commun., 2012, 48, 2152 DOI: 10.1039/C2CC16943F

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