Issue 12, 2012
From the journal:

Chemical Communications

Highly stereoselective synthesis of cis-β-enaminones mediated by diethyl azodicarboxylate†

Xiaoliang Xu,*a   Ping Du,a   Dongping Cheng,b   Hong Wanga  and  Xiaonian Li*a  

* Corresponding authors

a Institute of Industrial Catalysis, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 3100, People's Republic of China
E-mail: xuxiaoliang@zjut.edu.cn, xnli@zjut.edu.cn
Fax: +86 571 88320409
Tel: +86 571 88320409

b College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China

Abstract

Promoted by diethyl azodicarboxylate, a novel and highly stereoselective synthesis of cis-β-enaminones via oxidative dehydrogenation and hydration of the substituted propargylamines was realized. The possible mechanism was also proposed.

Graphical abstract: Highly stereoselective synthesis of cis-β-enaminones mediated by diethyl azodicarboxylate

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Article information

DOI
https://doi.org/10.1039/C2CC16997E
Article type
Communication
Submitted
11 Nov 2011
Accepted
08 Dec 2011
First published
12 Dec 2011

Chem. Commun., 2012,48, 1811-1813

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Highly stereoselective synthesis of cis-β-enaminones mediated by diethyl azodicarboxylate

X. Xu, P. Du, D. Cheng, H. Wang and X. Li, Chem. Commun., 2012, 48, 1811 DOI: 10.1039/C2CC16997E

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