Issue 28, 2012

Enhanced isosteric heat of H2adsorption by inclusion of crown ethers in a porous metal–organic framework

Abstract

Inclusion of 18-crown-6 or 15-crown-5 in a porous MOF increased the isosteric heats of H2 adsorption significantly, which are comparable to MOFs containing open metal sites.

Graphical abstract: Enhanced isosteric heat of H2 adsorption by inclusion of crown ethers in a porous metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
11 Nov 2011
Accepted
09 Feb 2012
First published
10 Feb 2012

Chem. Commun., 2012,48, 3400-3402

Enhanced isosteric heat of H2 adsorption by inclusion of crown ethers in a porous metal–organic framework

H. J. Park and M. P. Suh, Chem. Commun., 2012, 48, 3400 DOI: 10.1039/C2CC17005A

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