Issue 9, 2012
From the journal:

Chemical Communications

Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach†‡

S. M. Ibrahim Al-Rafia,a   Adam C. Malcolm,a   Robert McDonald,a   Michael J. Fergusona  and  Eric Rivard*a  

* Corresponding authors

a Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada
E-mail: erivard@ualberta.ca
Tel: +1 780-492-4255

Abstract

A stable Si(II) dihydride complex, IPr·SiH2·BH3 (IPr = [(HCNDipp)2C:]; Dipp = 2,6-iPr2C6H3), was synthesized and preliminary reactivity involving this source of encapsulated silylene is reported.

Graphical abstract: Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach

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Article information

DOI
https://doi.org/10.1039/C2CC17101E
Article type
Communication
Submitted
16 Nov 2011
Accepted
07 Dec 2011
First published
12 Dec 2011

Chem. Commun., 2012,48, 1308-1310

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Efficient generation of stable adducts of Si(II) dihydride using a donor–acceptor approach

S. M. I. Al-Rafia, A. C. Malcolm, R. McDonald, M. J. Ferguson and E. Rivard, Chem. Commun., 2012, 48, 1308 DOI: 10.1039/C2CC17101E

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