Issue 27, 2012

Chiral bicyclic [2.2.2] octadieneligands for Rh-catalysed catalytic asymmetric conjugate additions to acyclic enones: a quantitative structure–property relationship

Abstract

A series of chiral bicyclic [2.2.2]diene ligands gave variable ee values for Rh-catalysed asymmetric conjugate addition to an acyclic enone. The interplay between electronic and steric effects was captured in a robust predictive quantitative structure–property relationship (QSPR) model for enantioselectivity.

Graphical abstract: Chiral bicyclic [2.2.2] octadiene ligands for Rh-catalysed catalytic asymmetric conjugate additions to acyclic enones: a quantitative structure–property relationship

Supplementary files

Article information

Article type
Communication
Submitted
16 Nov 2011
Accepted
24 Dec 2011
First published
10 Jan 2012

Chem. Commun., 2012,48, 3279-3281

Chiral bicyclic [2.2.2] octadiene ligands for Rh-catalysed catalytic asymmetric conjugate additions to acyclic enones: a quantitative structure–property relationship

Y. Luo, N. G. Berry and A. J. Carnell, Chem. Commun., 2012, 48, 3279 DOI: 10.1039/C2CC17120A

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