Issue 16, 2012
From the journal:

Chemical Communications

Discovery of 2-aminobuta-1,3-enynes in asymmetric organocascade catalysis: construction of drug-like spirocyclic cyclohexanes having five to six contiguous stereocenters†‡

Dhevalapally B. Ramachary,*a   Chintalapudi Venkaiaha  and  Patoju Murali Krishnaa  

* Corresponding authors

a School of Chemistry, University of Hyderabad, Hyderabad-500 046, India
E-mail: ramsc@uohyd.ernet.in
Fax: +91-40-23012460

Abstract

We present herein for the first time the asymmetric synthesis of drug-like spiranes through reflexive-Michael reaction by using 2-aminobuta-1,3-enyne catalysis under mild conditions.

Graphical abstract: Discovery of 2-aminobuta-1,3-enynes in asymmetric organocascade catalysis: construction of drug-like spirocyclic cyclohexanes having five to six contiguous stereocenters

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Article information

DOI
https://doi.org/10.1039/C2CC17219D
Article type
Communication
Submitted
20 Nov 2011
Accepted
22 Dec 2011
First published
03 Jan 2012

Chem. Commun., 2012,48, 2252-2254

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Discovery of 2-aminobuta-1,3-enynes in asymmetric organocascade catalysis: construction of drug-like spirocyclic cyclohexanes having five to six contiguous stereocenters

D. B. Ramachary, C. Venkaiah and P. Murali Krishna, Chem. Commun., 2012, 48, 2252 DOI: 10.1039/C2CC17219D

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