Issue 30, 2012

Ring-size controllable metallamacrocycles as building blocks for the construction of microporous metal–organic frameworks

Abstract

Presented here is a new strategy for the synthesis of metallamacrocycles (MC[n]) with different ring-size and guest selectivity via integrating a flexible trinuclear metal unit and a bridging organic ligand, and further body-centered cubic packing of these MCs results in the formation of three microporous MOFs for potential application in gas storage.

Graphical abstract: Ring-size controllable metallamacrocycles as building blocks for the construction of microporous metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
22 Nov 2011
Accepted
15 Feb 2012
First published
17 Feb 2012

Chem. Commun., 2012,48, 3653-3655

Ring-size controllable metallamacrocycles as building blocks for the construction of microporous metal–organic frameworks

Z. Jiang, G. Jiang, F. Wang, Z. Zhao and J. Zhang, Chem. Commun., 2012, 48, 3653 DOI: 10.1039/C2CC17256A

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