Issue 20, 2012
From the journal:

Chemical Communications

Mechanochemical reactions of coordination polymers by grinding with KBr†

Mangayarkarasi Nagarathinam,a   Anjana Chanthapally,a   Saul H. Lapidus,b   Peter W. Stephens*b  and  Jagadese J. Vittal*ac  

* Corresponding authors

a Department of Chemistry, National University of Singapore, Singapore
E-mail: chmjjv@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6516 2975

b Department of Physics and Astronomy, Stony Brook University, Stony Brook, USA
E-mail: Peter.Stephens@stonybrook.edu
Fax: +1 631 632 8176
Tel: +1 631 632 8156

c Department of Chemistry, Gyeongsang National University, Jinju 660-701, S. Korea

Abstract

Grinding of a one-dimensional (1-D) ladder coordination polymer (CP), [Zn(μ-CH3CO2)(CF3CO2)bpe] (1), and a hydrogen-bonded 1-D CP, [Cd(CH3CO2)2bpe(H2O)] (2), with KBr resulted in the exchange of carboxylate by bromide ions and the formation of 1-D zigzag and 2-D CPs respectively.

Graphical abstract: Mechanochemical reactions of coordination polymers by grinding with KBr

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Article information

DOI
https://doi.org/10.1039/C2CC17358A
Article type
Communication
Submitted
25 Nov 2011
Accepted
10 Jan 2012
First published
01 Feb 2012

Chem. Commun., 2012,48, 2585-2587

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Mechanochemical reactions of coordination polymers by grinding with KBr

M. Nagarathinam, A. Chanthapally, S. H. Lapidus, P. W. Stephens and J. J. Vittal, Chem. Commun., 2012, 48, 2585 DOI: 10.1039/C2CC17358A

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