Issue 33, 2012
From the journal:

Chemical Communications

Metal array fabrication through self-assembly of Pt-complex-bound amino acids†

Katsuhiro Isozaki,abc   Kazuki Ogata,ad   Yusuke Haga,c   Daisuke Sasano,ad   Tetsuya Ogawa,e   Hiroki Kurata,e   Masaharu Nakamura,ad   Takeshi Naota*c  and  Hikaru Takaya*acdf  

* Corresponding authors

a International Research Center for Elements Science, Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan
E-mail: takaya@scl.kyoto-u.ac.jp
Fax: +81-774-38-3186
Tel: +81-774-38-3182

b Polymer Materials Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan

c Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-8531, Japan

d Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Uji, Kyoto 611-0011, Japan

e Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan

f PRESTO, Japan Science and Technology Agency, Japan

Abstract

A new type of Pt-complex-bound amino acid was synthesized by condensation of a cyclometalated Pt complex with the side-chain residue of N- and C-alkylated glutamic acid. Self-assembly of the Pt-bound lipophilic amino acid afforded a supramolecular gel in organic solvents, which comprised fibrous lamellar aggregates that supported a highly oriented Pt array.

Graphical abstract: Metal array fabrication through self-assembly of Pt-complex-bound amino acids

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Article information

DOI
https://doi.org/10.1039/C2CC17530D
Article type
Communication
Submitted
02 Dec 2011
Accepted
04 Jan 2012
First published
02 Feb 2012

Chem. Commun., 2012,48, 3936-3938

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Metal array fabrication through self-assembly of Pt-complex-bound amino acids

K. Isozaki, K. Ogata, Y. Haga, D. Sasano, T. Ogawa, H. Kurata, M. Nakamura, T. Naota and H. Takaya, Chem. Commun., 2012, 48, 3936 DOI: 10.1039/C2CC17530D

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