Issue 27, 2012

Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

Abstract

The first report of a biocatalytic regioselective oxidative mono-cleavage of dialkenes was successfully achieved employing a cell-free enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities.

Graphical abstract: Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

Supplementary files

Article information

Article type
Communication
Submitted
04 Dec 2011
Accepted
10 Feb 2012
First published
10 Feb 2012

Chem. Commun., 2012,48, 3303-3305

Expanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

C. E. Paul, A. Rajagopalan, I. Lavandera, V. Gotor-Fernández, W. Kroutil and V. Gotor, Chem. Commun., 2012, 48, 3303 DOI: 10.1039/C2CC17572J

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